MWW-Type Titanosilicate Synthesis, Structural Modification and Catalytic Applications to Green Oxidations
| Author/creator | Wu, Peng Author |
| Format | Electronic |
| Publication Info | New York : Springer |
| Description | 128 p. ill 23.500 x 015.500 cm. |
| Supplemental Content | Full text available from eBooks on EBSCOhost |
| Other author/creator | Xu, Hao Author |
| Other author/creator | Xu, Le Author |
| Other author/creator | Liu, Yueming Author |
| Other author/creator | He, Mingyuan Author |
| Series | SpringerBriefs in Molecular Science / SpringerBriefs in Green Chemistry for Sustainability Ser. |
| Summary | Annotation This book provides a comprehensive review of a new generation of selective oxidationtitanosilicate catalysts with theMWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phaseisomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayersilylation to obtain a novel structure with larger porosity. In the selective oxidation (alkeneepoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventionaltitanosilicates such as TS-1 and Ti-Beta. |
| Access restriction | Available only to authorized users. |
| Technical details | Mode of access: World Wide Web |
| Genre/form | Electronic books. |
| ISBN | 9783642391149 |
| ISBN | 3642391141 (Trade Paper) Active Record |
| Standard identifier# | 9783642391149 |
| Stock number | 10.1007/978-3-642-39115-6 00024965 |
Availability
| Library | Location | Call Number | Status | Item Actions |
|---|---|---|---|---|
| Electronic Resources | Access Content Online | ✔ Available |