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010 a| 2018300724;

020 a| 9780128112205 (pbk.);

020 a| 0128112204 (pbk.);

035 a| (WaSeSS)ssj0002062636;

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049 a| EREEa| NEHH;

050 00 a| QC454.M6b| F75 2018;

082 00 a| 543/.542| 23/eng/20230920;

245 00 a| Frontiers and advances in molecular spectroscopyh| [electronic resource] /c| edited by Jaan Laane.;

246 30 a| Molecular spectroscopy;

260 a| Amsterdam, Netherlands :b| Elsevier,c| [2018];

300 a| xxi, 763 pages :b| illustrations ;c| 23 cm;

504 a| Includes bibliographical references and index.;

505 00 a| Note continued:g| 6.2.t| SERS Detection and Identification of Bacteremia Developments --g| 7.t| Origins of Bacterial SERS Signals --g| 7.1.t| Chemical/Molecular Origins of the SERS Spectra of Bacteria --g| 7.2.t| Purines Dominate the Bacterial SERS Spectra --g| 7.3.t| Biochemical Origins of the SERS Spectra of Bacteria --g| 7.4.t| Chemical and Biochemical Origins of SERS Spectra of STD Pathogens --g| 8.t| Forensics --g| 8.1.t| Introduction --g| 8.2.t| SERS Detection and Identification of Human Body Fluids --g| 9.t| Conclusion --t| Acknowledgments --t| References --g| 11.t| Quantitative Spectrometry of Complex Molecular Systems by Hypothetical Addition Multivariate Analysis With Numerical Differentiation (HAMAND) /r| Hiro-o Hamaguchi --g| 1.t| Introduction --g| 2.t| The Principle of HAMAND --g| 3.t| Mathematical Procedure --g| 4.t| Applications of HAMAND --g| 4.1.t| Solution Sample --g| 4.2.t| Solid Sample --g| 4.3.t| Forensic Sample --g| 5.t| Discussion --t| Acknowledgments --t| References --g| 12.t| Progress in FAST CARS Toward Quantum Biophotonics /r| Marian O. Scully --g| 1.t| Introduction --g| 2.t| Basic Principles of FAST CARS --g| 3.t| Applications to Biosensing --g| 4.t| Versatile FAST CARS --g| 5.t| Heterodyne Single-Beam FAST CARS Microscopy --g| 6.t| FAST CARS With Surface Enhancement --g| 7.t| Conclusion --t| Acknowledgments --t| References --g| 13.t| Coherent Raman Generation in Solid-State Materials Using Spatial and Temporal Laser Field Shaping /r| Alexei V. Sokolov --g| 1.t| Introduction --g| 2.t| Basic Principles of Molecular Modulation --g| 3.t| Broadband Coherent Light Generation in the Raman-Active Crystal PbWO4 --g| 3.1.t| Introduction --g| 3.2.t| Coherent Raman Generation via Two-Color Laser Fields --g| 3.3.t| Coherent Raman Generation via Three-Color Laser Fields --g| 3.4.t| Coherent Raman Generation via Linearly Chirped Pulses --g| 4.t| Using Molecular Modulation to Obtain an Ultrafast Pulse --g| 4.1.t| Introduction --g| 4.2.t| Manipulating Raman Sideband Phase via Commercial Pulse Shaper --g| 4.3.t| Manipulating Raman Sideband Phase via Spherical Mirrors --g| 5.t| The Raman Process With Optical Vortices --g| 5.1.t| Introduction --g| 5.2.t| Topological Charge Transfer --g| 5.3.t| Experiments With Single-Charged Pump/Stokes --g| 5.4.t| Experiments With Multiply Charged Pump/Stokes --g| 6.t| Summary --t| References --t| Further Reading --g| 14.t| Vibrational Optical Activity: From Small Chiral Molecules to Protein Pharmaceuticals and Beyond /r| Laurence A. Nafie --g| 1.t| Introduction --g| 1.1.t| Overview of VOA History --g| 1.2.t| Overview of the Current State of the Art --g| 2.t| Vibrational Circular Dichroism --g| 2.1.t| Theory --g| 2.2.t| Instrumentation and Measurement --g| 2.3.t| Calculations --g| 2.4.t| Established Applications --g| 2.5.t| Frontiers of VCD --g| 3.t| Raman Optical Activity --g| 3.1.t| Theory --g| 3.2.t| Instrumentation and Measurement --g| 3.3.t| Calculations --g| 3.4.t| Established Applications --g| 3.5.t| Frontiers of ROA --g| 4.t| Complementarity of VCD and ROA --g| 5.t| Conclusions and Summary --g| 5.1.t| VCD Frontiers --g| 5.2.t| ROA Frontiers --g| 5.3.t| Chiroptical Spectroscopy Frontiers --t| References --g| 15.t| High-Resolution Laboratory Terahertz Spectroscopy and Applications to Astrophysics /r| Stephan Schlemmer --g| 1.t| Introduction --g| 2.t| Molecules in Astrophysical Observations --g| 2.1.t| Complex Organic Molecules in Space --g| 2.2.t| Molecular Ions in Space --g| 3.t| Terahertz Absorption Spectroscopy --g| 4.t| Action Spectroscopy of Ions in Cold Traps --g| 4.1.t| LIR Infrared Spectroscopy --g| 4.2.t| IR/THz Double Resonance Spectroscopy --g| 4.3.t| Frequency Comb Based Spectra --g| 4.4.t| LIR Intensities --g| 5.t| Future Trends in THz Spectroscopy --g| 5.1.t| LIR Schemes --g| 5.2.t| Different Experimental Approaches --t| Acknowledgments --t| References --g| 16.t| Studying Interaction, Ion-Pair Formation, and Mixing Behavior of Protic Ionic Liquids by Means of Far-Infrared Spectroscopy /r| Ralf Ludwig --g| 1.t| Introduction --g| 2.t| FIR Spectroscopy --g| 3.t| Protic Ionic Liquids --g| 4.t| The Subtle Balance of Coulomb Interaction, Hydrogen Bonding and Dispersion Forces --g| 4.1.t| Detecting and Quantifying H-Bonds --g| 4.2.t| Pure Interaction by Removing Reduced Mass Effects --g| 4.3.t| The Influence of Dispersion Forces on the FIR Spectra --g| 4.4.t| Dispersion Forces Compete With Hydrogen Bonds --g| 5.t| Ion Speciation --g| 5.1.t| Ion Speciation in Water --g| 5.2.t| Ion Pair Formation in Dimethylsulfoxide (DMSO) --g| 5.3.t| Reformation of Contact Ion Pairs With Increasing Temperature --g| 6.t| Mixing Behavior --g| 6.1.t| Nonideal Mixing Behavior Due to Hydrogen Bonds --g| 6.2.t| Cluster Formation Controls Macroscopic Properties --g| 7.t| Conclusions --t| References --g| 17.t| Advancements in Microwave Spectroscopy /r| Jens-Uwe Grabow --g| 1.t| Introduction --g| 2.t| Technical Advancements --g| 2.1.t| Chiral Discrimination --g| 2.2.t| Diffusion of Chirp- and Tone-Excitation Fourier Transform Spectrometers --g| 3.t| Molecular Systems --g| 3.1.t| Chemical Information From MW --g| 3.2.t| Internal Dynamics --g| 4.t| Astrochemistry --g| 4.1.t| Laboratory Investigations --g| 4.2.t| Detection in the Interstellar Space --t| Acknowledgments --t| References --g| 18.t| Nitric Oxide Laser-Induced Fluorescence Imaging Methods and Their Application to Study High-Speed Flows /r| Simon W. North --g| 1.t| Introduction --g| 2.t| Nitric Oxide Laser Induced Fluorescence --g| 2.1.t| Temperature Measurements Using NO Fluorescence: Two-Line NO PLIF --g| 2.2.t| Velocity Measurements Using Molecular Tagging Techniques: NO Fluorescence MTV --g| 3.t| Experimental Measurements --g| 3.1.t| NO2 Photodissociation MTV --g| 3.2.t| Temperature Measurements Using NO2 Photodissociation --g| 3.3.t| Simultaneous Measurement of Velocity and Temperature --g| 3.4.t| The "Invisible Ink" VENOM Variant --g| 4.t| Conclusions --t| References --g| 19.t| Photogeneration of Rare Molecules in Cryogenic Matrices: Spectroscopists' Adventures in Wonderland /r| Rui Fausto --g| 1.t| Introduction --g| 2.t| Act I -- Narrowband IR-Induced Transformations --g| 2.1.t| Scene 1.1: The Case of 2-Fluorobenzoic Acid --g| 2.2.t| Scene 1.2: Glycolic Acid -- Probing Consecutive Conformational Isomerizations --g| 2.3.t| Scene 1.3: The Genesis of Rare Dimers of Acetic Acid --g| 2.4.t| Scene 1.4: Conformational Switching by Excitation of a Remote Bond --g| 3.t| Act II -- Narrowband UV-Induced Transformations --g| 3.1.t| Scene 11.1: p-Anisaldehyde -- Dependence of the Photostationary State Position on the Wavelength --g| 3.2.t| Scene II.2: Bond-Shift Isomers of 1,3-Dipolar Species (Nitrile Imines) --g| 3.3.t| Scene II.3: Photoproduction of a Rare Spiro-2H-Azirine --g| 3.4.t| Scene II.4: First Observation of a Nitrene Tunneling Reaction --g| 4.t| Conclusion --t| Acknowledgements --t| References --g| 20.t| Matrix Isolation Spectroscopic Studies: Thermal and Soft Photochemical Bimolecular Reactions /r| Bruce S. Ault --g| 1.t| Introduction and Scope --g| 2.t| Introduction to Matrix Isolation and Experimental Details --g| 2.1.t| Cryogenics and Vacuum Hardware --g| 2.2.t| Preparation of Reactive Intermediates --g| 2.3.t| Applications of Computational Chemistry --g| 3.t| Thermal Reactions and Complex Formation --g| 3.1.t| Hydrogen-Bonded Complexes --g| 3.2.t| Intermediate Lewis Acid-Base Complexes --g| 3.3.t| Reactions of Diborane --g| 3.4.t| Reactions of Chromyl Chloride and Metal Oxo Compounds --g| 4.t| Ozonolysis of Alkenes --g| 4.1.t| cis-2-Butene --g| 4.2.t| Cyclopentene and Cyclopentadiene --g| 4.3.t| Ethene and Propene --g| 4.4.t| Bicylic Alkenes --g| 4.5.t| 1,3- and 1,4-Cyclohexadiene: A Non-Criegee Mechanism --g| 5.t| Reaction of Ozone With Volatile Organometallic Compounds --g| 5.1.t| Introduction and Dimethylzinc --g| 5.2.t| Dimethylcadmium --g| 5.3.t| Trimethyl Metals --g| 5.4.t| Metallocenes --g| 6.t| Soft Photochemical Reactions --g| 6.1.t| Ozone Reaction With Ferrocene --g| 6.2.t| Electronic Spectroscopy --g| 7.t| Conclusions --t| Acknowledgments --t| References --t| Further Reading --g| 21.t| Theory of Enantiomer-Specific Microwave Spectroscopy /r| Kevin K. Lehmann --g| 1.t| Introduction --g| 2.t| Stark Induced Chiral Emission --g| 2.1.t| Signals in the Perturbative Limit --g| 2.2.t| High Stark Field Mixing --g| 2.3.t| Effect of Variation in Excitation Strength --g| 3.t| Three Wave Mixing --g| 3.1.t| Polarization Calculation --g| 3.2.t| The Effects of Lack of Phase Matching --g| 4.t| Some Extensions --g| 5.t| Conclusions --t| Acknowledgments --t| References.;

506 a| Available only to authorized users.;

538 a| Mode of access: World Wide Web;

650 0 a| Molecular spectroscopy.=| ^A54357;

650 7 a| Molecular spectroscopy.2| fast0| (OCoLC)fst01024838;

655 0 a| Electronic books.=| ^A491897;

700 1 a| Laane, Jaan.=| ^A790427;

856 40 z| Full text available from eBook - Chemistry 2017 [EBCC17]u| https://go.openathens.net/redirector/ecu.edu?url=https%3A%2F%2Fwww.sciencedirect.com%2Fscience%2Fbook%2F9780128112205;

947 a| (OCoLC)ocn983303362;

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949 a| CLICK ON WEB ADDRESSw| ASISh| JMUSIC60;

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998 a| 5243232;

999 a| CLICK ON WEB ADDRESSw| ASISc| 1i| 5243232-1001l| JNETm| JOYNERr| Ys| Yt| JNESSBKu| 2/13/2020x| EBOOKz| JERESOURCE;

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Frontiers and advances in molecular spectroscopy / edited by Jaan Laane.

Other author	Laane, Jaan.
Format	Electronic
Publication Info	Amsterdam, Netherlands : Elsevier, [2018]
Description	xxi, 763 pages : illustrations ; 23 cm
Supplemental Content	Full text available from eBook - Chemistry 2017 [EBCC17]
Subjects	Molecular spectroscopy.

Portion of title	Molecular spectroscopy
Contents	Note continued: 6.2. SERS Detection and Identification of Bacteremia Developments -- 7. Origins of Bacterial SERS Signals -- 7.1. Chemical/Molecular Origins of the SERS Spectra of Bacteria -- 7.2. Purines Dominate the Bacterial SERS Spectra -- 7.3. Biochemical Origins of the SERS Spectra of Bacteria -- 7.4. Chemical and Biochemical Origins of SERS Spectra of STD Pathogens -- 8. Forensics -- 8.1. Introduction -- 8.2. SERS Detection and Identification of Human Body Fluids -- 9. Conclusion -- Acknowledgments -- References -- 11. Quantitative Spectrometry of Complex Molecular Systems by Hypothetical Addition Multivariate Analysis With Numerical Differentiation (HAMAND) / Hiro-o Hamaguchi -- 1. Introduction -- 2. The Principle of HAMAND -- 3. Mathematical Procedure -- 4. Applications of HAMAND -- 4.1. Solution Sample -- 4.2. Solid Sample -- 4.3. Forensic Sample -- 5. Discussion -- Acknowledgments -- References -- 12. Progress in FAST CARS Toward Quantum Biophotonics / Marian O. Scully -- 1. Introduction -- 2. Basic Principles of FAST CARS -- 3. Applications to Biosensing -- 4. Versatile FAST CARS -- 5. Heterodyne Single-Beam FAST CARS Microscopy -- 6. FAST CARS With Surface Enhancement -- 7. Conclusion -- Acknowledgments -- References -- 13. Coherent Raman Generation in Solid-State Materials Using Spatial and Temporal Laser Field Shaping / Alexei V. Sokolov -- 1. Introduction -- 2. Basic Principles of Molecular Modulation -- 3. Broadband Coherent Light Generation in the Raman-Active Crystal PbWO4 -- 3.1. Introduction -- 3.2. Coherent Raman Generation via Two-Color Laser Fields -- 3.3. Coherent Raman Generation via Three-Color Laser Fields -- 3.4. Coherent Raman Generation via Linearly Chirped Pulses -- 4. Using Molecular Modulation to Obtain an Ultrafast Pulse -- 4.1. Introduction -- 4.2. Manipulating Raman Sideband Phase via Commercial Pulse Shaper -- 4.3. Manipulating Raman Sideband Phase via Spherical Mirrors -- 5. The Raman Process With Optical Vortices -- 5.1. Introduction -- 5.2. Topological Charge Transfer -- 5.3. Experiments With Single-Charged Pump/Stokes -- 5.4. Experiments With Multiply Charged Pump/Stokes -- 6. Summary -- References -- Further Reading -- 14. Vibrational Optical Activity: From Small Chiral Molecules to Protein Pharmaceuticals and Beyond / Laurence A. Nafie -- 1. Introduction -- 1.1. Overview of VOA History -- 1.2. Overview of the Current State of the Art -- 2. Vibrational Circular Dichroism -- 2.1. Theory -- 2.2. Instrumentation and Measurement -- 2.3. Calculations -- 2.4. Established Applications -- 2.5. Frontiers of VCD -- 3. Raman Optical Activity -- 3.1. Theory -- 3.2. Instrumentation and Measurement -- 3.3. Calculations -- 3.4. Established Applications -- 3.5. Frontiers of ROA -- 4. Complementarity of VCD and ROA -- 5. Conclusions and Summary -- 5.1. VCD Frontiers -- 5.2. ROA Frontiers -- 5.3. Chiroptical Spectroscopy Frontiers -- References -- 15. High-Resolution Laboratory Terahertz Spectroscopy and Applications to Astrophysics / Stephan Schlemmer -- 1. Introduction -- 2. Molecules in Astrophysical Observations -- 2.1. Complex Organic Molecules in Space -- 2.2. Molecular Ions in Space -- 3. Terahertz Absorption Spectroscopy -- 4. Action Spectroscopy of Ions in Cold Traps -- 4.1. LIR Infrared Spectroscopy -- 4.2. IR/THz Double Resonance Spectroscopy -- 4.3. Frequency Comb Based Spectra -- 4.4. LIR Intensities -- 5. Future Trends in THz Spectroscopy -- 5.1. LIR Schemes -- 5.2. Different Experimental Approaches -- Acknowledgments -- References -- 16. Studying Interaction, Ion-Pair Formation, and Mixing Behavior of Protic Ionic Liquids by Means of Far-Infrared Spectroscopy / Ralf Ludwig -- 1. Introduction -- 2. FIR Spectroscopy -- 3. Protic Ionic Liquids -- 4. The Subtle Balance of Coulomb Interaction, Hydrogen Bonding and Dispersion Forces -- 4.1. Detecting and Quantifying H-Bonds -- 4.2. Pure Interaction by Removing Reduced Mass Effects -- 4.3. The Influence of Dispersion Forces on the FIR Spectra -- 4.4. Dispersion Forces Compete With Hydrogen Bonds -- 5. Ion Speciation -- 5.1. Ion Speciation in Water -- 5.2. Ion Pair Formation in Dimethylsulfoxide (DMSO) -- 5.3. Reformation of Contact Ion Pairs With Increasing Temperature -- 6. Mixing Behavior -- 6.1. Nonideal Mixing Behavior Due to Hydrogen Bonds -- 6.2. Cluster Formation Controls Macroscopic Properties -- 7. Conclusions -- References -- 17. Advancements in Microwave Spectroscopy / Jens-Uwe Grabow -- 1. Introduction -- 2. Technical Advancements -- 2.1. Chiral Discrimination -- 2.2. Diffusion of Chirp- and Tone-Excitation Fourier Transform Spectrometers -- 3. Molecular Systems -- 3.1. Chemical Information From MW -- 3.2. Internal Dynamics -- 4. Astrochemistry -- 4.1. Laboratory Investigations -- 4.2. Detection in the Interstellar Space -- Acknowledgments -- References -- 18. Nitric Oxide Laser-Induced Fluorescence Imaging Methods and Their Application to Study High-Speed Flows / Simon W. North -- 1. Introduction -- 2. Nitric Oxide Laser Induced Fluorescence -- 2.1. Temperature Measurements Using NO Fluorescence: Two-Line NO PLIF -- 2.2. Velocity Measurements Using Molecular Tagging Techniques: NO Fluorescence MTV -- 3. Experimental Measurements -- 3.1. NO2 Photodissociation MTV -- 3.2. Temperature Measurements Using NO2 Photodissociation -- 3.3. Simultaneous Measurement of Velocity and Temperature -- 3.4. The "Invisible Ink" VENOM Variant -- 4. Conclusions -- References -- 19. Photogeneration of Rare Molecules in Cryogenic Matrices: Spectroscopists' Adventures in Wonderland / Rui Fausto -- 1. Introduction -- 2. Act I -- Narrowband IR-Induced Transformations -- 2.1. Scene 1.1: The Case of 2-Fluorobenzoic Acid -- 2.2. Scene 1.2: Glycolic Acid -- Probing Consecutive Conformational Isomerizations -- 2.3. Scene 1.3: The Genesis of Rare Dimers of Acetic Acid -- 2.4. Scene 1.4: Conformational Switching by Excitation of a Remote Bond -- 3. Act II -- Narrowband UV-Induced Transformations -- 3.1. Scene 11.1: p-Anisaldehyde -- Dependence of the Photostationary State Position on the Wavelength -- 3.2. Scene II.2: Bond-Shift Isomers of 1,3-Dipolar Species (Nitrile Imines) -- 3.3. Scene II.3: Photoproduction of a Rare Spiro-2H-Azirine -- 3.4. Scene II.4: First Observation of a Nitrene Tunneling Reaction -- 4. Conclusion -- Acknowledgements -- References -- 20. Matrix Isolation Spectroscopic Studies: Thermal and Soft Photochemical Bimolecular Reactions / Bruce S. Ault -- 1. Introduction and Scope -- 2. Introduction to Matrix Isolation and Experimental Details -- 2.1. Cryogenics and Vacuum Hardware -- 2.2. Preparation of Reactive Intermediates -- 2.3. Applications of Computational Chemistry -- 3. Thermal Reactions and Complex Formation -- 3.1. Hydrogen-Bonded Complexes -- 3.2. Intermediate Lewis Acid-Base Complexes -- 3.3. Reactions of Diborane -- 3.4. Reactions of Chromyl Chloride and Metal Oxo Compounds -- 4. Ozonolysis of Alkenes -- 4.1. cis-2-Butene -- 4.2. Cyclopentene and Cyclopentadiene -- 4.3. Ethene and Propene -- 4.4. Bicylic Alkenes -- 4.5. 1,3- and 1,4-Cyclohexadiene: A Non-Criegee Mechanism -- 5. Reaction of Ozone With Volatile Organometallic Compounds -- 5.1. Introduction and Dimethylzinc -- 5.2. Dimethylcadmium -- 5.3. Trimethyl Metals -- 5.4. Metallocenes -- 6. Soft Photochemical Reactions -- 6.1. Ozone Reaction With Ferrocene -- 6.2. Electronic Spectroscopy -- 7. Conclusions -- Acknowledgments -- References -- Further Reading -- 21. Theory of Enantiomer-Specific Microwave Spectroscopy / Kevin K. Lehmann -- 1. Introduction -- 2. Stark Induced Chiral Emission -- 2.1. Signals in the Perturbative Limit -- 2.2. High Stark Field Mixing -- 2.3. Effect of Variation in Excitation Strength -- 3. Three Wave Mixing -- 3.1. Polarization Calculation -- 3.2. The Effects of Lack of Phase Matching -- 4. Some Extensions -- 5. Conclusions -- Acknowledgments -- References.
Bibliography note	Includes bibliographical references and index.
Access restriction	Available only to authorized users.
Technical details	Mode of access: World Wide Web
Genre/form	Electronic books.
LCCN	2018300724
ISBN	9780128112205 (pbk.)
ISBN	0128112204 (pbk.)

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